Syntheses, Luminescence Switching, and Electrochemical Studies of Photochromic Dithienyl-1,10-phenanthroline Zinc(II) Bis(thiolate) Complexes
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下载链接：
https://figshare.com/articles/dataset/Syntheses_Luminescence_Switching_and_Electrochemical_Studies_of_Photochromic_Dithienyl_1_10_phenanthroline_Zinc_II_Bis_thiolate_Complexes/3025654
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资源简介：
A series of zinc(II) diimine bis(thiolate) complexes with photochromic diarylethene-containing phenanthroline ligands
was synthesized, and their photophysical and photochromic properties were studied. The X-ray crystal structures
of two of these complexes have been characterized. All complexes exhibit strong 3LLCT phosphorescence at
510−620 nm in the solid state at 77 and 298 K and in EtOH−MeOH glass at 77 K. Detailed studies revealed that
the absorption, emission, and electrochemical properties of the complexes could be readily switched via the
photochromic ring-closing and ring-opening reactions.
创建时间：
2016-02-29
