Conjugate Addition/Ireland−Claisen Rearrangements of Allyl Fumarates: Simple Access to Terminally Differentiated Succinates
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https://figshare.com/articles/dataset/Conjugate_Addition_Ireland_Claisen_Rearrangements_of_Allyl_Fumarates_Simple_Access_to_Terminally_Differentiated_Succinates/2957041
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资源简介：
The conjugate addition of dialkylzinc reagents to allyl
fumarates with subsequent Ireland−Claisen rearrangement
has been accomplished yielding substituted unsymmetrical
succinic acid derivatives. This one-pot reaction creates two
new carbon−carbon bonds at contiguous stereogenic centers.
The reaction proceeds for several alkylzinc reagents and
substituted allyl fumarates. The products contain distinguishable functional handles for further manipulation.
创建时间：
2016-06-03
