Conjugate Addition/Ireland−Claisen Rearrangements of Allyl Fumarates: Simple Access to Terminally Differentiated Succinates
收藏NIAID Data Ecosystem2026-03-06 收录
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The conjugate addition of dialkylzinc reagents to allyl fumarates with subsequent Ireland−Claisen rearrangement has been accomplished yielding substituted unsymmetrical succinic acid derivatives. This one-pot reaction creates two new carbon−carbon bonds at contiguous stereogenic centers. The reaction proceeds for several alkylzinc reagents and substituted allyl fumarates. The products contain distinguishable functional handles for further manipulation.
创建时间：
2016-06-03
