A Luminescent Silver(I) Carbene Stair Polymer
收藏NIAID Data Ecosystem2026-03-06 收录
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1-(9-Anthracenylmethyl)-3-ethylimidazolium iodide was heated in CH2Cl2 solution with silver oxide to afford a stair polymer of N-heterocyclic carbene silver(I), which gave strong anthracene-type fluorescence. The carbene moiety could be displaced from this polymer by pyridine to afford a known polymer with a similar shape but a tighter framework; this polymer showed an emission band at 579 nm arising from a Ag−Ag interaction.
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2016-08-26
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