Gold and Rhodium Transmetalation: Mechanistic Insights and Dual-Metal Reactivity
收藏Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Gold_and_Rhodium_Transmetalation_Mechanistic_Insights_and_Dual_Metal_Reactivity/2666731
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资源简介：
A transmetalation reaction between rhodium(III) and sp2- and sp3-hybridized organogold(I) compounds proceeds rapidly at ambient temperature (15 min to 6 h). Mechanistic experiments demonstrate that ligand dissociation on rhodium(III) precedes transmetalation; synthetic applications of the gold/rhodium transmetalation are highlighted by linking rhodium-mediated C−H activation, conjugate addition, and reductive elimination to transmetalation from organogold compounds.
创建时间：
2016-02-23
