Gold and Rhodium Transmetalation: Mechanistic Insights and Dual-Metal Reactivity
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A transmetalation reaction between rhodium(III) and sp2- and sp3-hybridized organogold(I) compounds proceeds rapidly at ambient temperature (15 min to 6 h). Mechanistic experiments demonstrate that ligand dissociation on rhodium(III) precedes transmetalation; synthetic applications of the gold/rhodium transmetalation are highlighted by linking rhodium-mediated C−H activation, conjugate addition, and reductive elimination to transmetalation from organogold compounds.
创建时间：
2016-02-23
