Cobalt Catalysis for Enantioselective Cyclobutanone Construction
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https://figshare.com/articles/dataset/Cobalt_Catalysis_for_Enantioselective_Cyclobutanone_Construction/5207770
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资源简介:
Over the past 40 years, intramolecular
hydroacylation has favored
five-membered rings, in preference to four membered rings. Herein,
we report a catalyst derived from earth-abundant cobalt that enables
preparation of cyclobutanones, with excellent regio-, diastereo-,
and enantiocontrol, under mild conditions (2 mol % catalyst loading
and as low as 50 °C).
创建时间:
2017-07-19



