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Enhancing Proton Conduction in 2D Co–La Coordination Frameworks by Solid-State Phase Transition

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https://figshare.com/articles/dataset/Enhancing_Proton_Conduction_in_2D_Co_La_Coordination_Frameworks_by_Solid_State_Phase_Transition/2278732
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We report that a new 2D 3d–4f phosphonate [CoIIILaIII(notpH)­(H2O)6]­ClO4·5H2O (CoLa-II) can undergo a phase transition above 45 °C and 93% relative humidity, resulting in [H3O]­[CoLa­(notp)­(H2O)4]­ClO4·3H2O (CoLa-III). The transition is accompanied by the release of the proton from intralayer to interlayer, and thus the proton conductivity of the material is increased by 1 order of magnitude.
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2016-02-17
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