A Unique Organolanthanide Cluster Containing Bulky Cyclooctatetraenyl Ligands
收藏Figshare2007-09-10 更新2026-04-28 收录
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https://figshare.com/articles/dataset/A_Unique_Organolanthanide_Cluster_Containing_Bulky_Cyclooctatetraenyl_Ligands/12067764
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The reaction of anhydrous PrCl3 with Li2(COT‘ ‘) (COT‘ ‘ = 1,4-bis(trimethylsilyl)cyclooctatetraenyl) in THF solution afforded an unprecedented cluster-centered Pr/Li multidecker sandwich complex of composition [Pr(COT‘ ‘)]2[Pr2(COT‘ ‘)2]2Li2(THF)2Cl8 (1), in which a central cube of eight Cl atoms is capped by two [Pr(COT‘ ‘)]+ half-sandwich and two [Pr2(COT‘ ‘)2]2+ sandwich units as well as two [Li(THF)]+ moieties.
创建时间：
2007-09-10
