Benzothiazines in Synthesis. Toward the Synthesis of Pseudopteroxazole
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The tricyclic benzothiazine 15 was prepared in a straightforward fashion via a completely stereoselective intramolecular Friedel−Crafts alkylation. This compound represents a potential precursor to the antitubercular agent, pseudopteroxazole. Its synthesis proceeded via a completely selective, intramolecular addition of a sulfoximine-stabilized carbanion to an α,β-unsaturated ester, followed by functional group manipulations.
创建时间：
2016-05-12
