An Arylative Ring Expansion Cascade of Fused Cyclobutenes via Short-Lived Intermediates with Planar Chirality
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https://figshare.com/articles/dataset/An_Arylative_Ring_Expansion_Cascade_of_Fused_Cyclobutenes_via_Short_Lived_Intermediates_with_Planar_Chirality/2144437
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资源简介：
An arylative ring
expansion cascade has been developed for the
synthesis of medium-sized carbocycles from fused cyclobutenes. This
reaction proceeds through a short-lived cis,trans-cycloalkadiene intermediate that is formed by thermal
4π electrocyclic ring opening. Chirality transfer experiments
provide direct evidence for the transient generation of the intermediate.
创建时间：
2016-02-13
