Disentangling Disorder in the Three-Dimensional Coordination Network of {Ag<sub>3</sub>[Tris(2-pyridylmethyl)cyclotriguaiacylene]<sub>2</sub>}(PF<sub>6</sub>)<sub>3</sub>
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The crystalline complex {Ag3[Tris(2-pyridylmethyl)cyclotriguaiacylene]2}(PF6)3 has been synthesized and shown by X-ray crystallography to have a disordered three-dimensional cubic coordination network structure. The coordination network features a back-to-back stacking of the molecular host-type ligands into tetrahedral clusters, and the PF6- anions act as both intracavity guests and lattice-type guests. Disentangling the network disorder gives a 4-fold interpenetrating (10,3)-a net.
创建时间:
2005-07-06



