Synthesis of Substituted Azulenes via Pt(II)-Catalyzed Ring-Expanding Cycloisomerization
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https://figshare.com/articles/dataset/Synthesis_of_Substituted_Azulenes_via_Pt_II_Catalyzed_Ring_Expanding_Cycloisomerization/2257894
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资源简介：
Substituted
azulenes, valuable structures for electronic devices
and pharmaceuticals, have been synthesized by the platinum(II)-catalyzed
intramolecular ring-expanding cycloisomerization of 1-en-3-yne with
ortho-disubstituted benzene. This novel method provides an alternative
route for the efficient synthesis of substituted azulenes. The reaction
mechanism of selected catalytic transformations was explored using
density functional calculations.
创建时间：
2016-02-16
