A Reductive-Heck Approach to the Hydroazulene Ring System: A Formal Synthesis of the Englerins
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https://figshare.com/articles/dataset/A_Reductive_Heck_Approach_to_the_Hydroazulene_Ring_System_A_Formal_Synthesis_of_the_Englerins/2507410
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资源简介：
The reduction of a palladium enolate prior to β-hydride elimination provides a unique reaction for the synthesis of the hydroazulene ring system. When combined with a transannular epoxide rearrangement cascade, the reductive-Heck reaction allows rapid entry to the oxo-bridged guaiane core of the englerins.
创建时间：
2012-07-06
