Structure, Stability, and Catalytic Activity of Fluorine-Bridged Complexes IPr·GaCl2(μ-F)EFn–1 (EFn– = SbF6–, PF6–, or BF4–)
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https://figshare.com/articles/dataset/Structure_Stability_and_Catalytic_Activity_of_Fluorine_Bridged_Complexes_IPr_GaCl_sub_2_sub_F_EF_sub_i_n_i_1_sub_EF_sub_i_n_i_sub_sup_sup_SbF_sub_6_sub_sup_sup_PF_sub_6_sub_sup_sup_or_BF_sub_4_sub_sup_sup_/2562256
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Fluorine-bridged NHC–gallium(III) complexes of the type IPr·GaCl2(μ-F)EFn–1 [IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene, and EFn = SbF6 or BF4] have been synthesized and characterized in solution and in the solid state. The [BF4]− adduct readily decomposes into gallium fluorides of the type [IPr·GaClmF3–m] (m = 0, 1, or 2) with release of gaseous BF3. These results corroborate the trend observed in IPr·GaCl3/AgEFn-catalyzed reactions in which a strong anion effect exists.
创建时间：
2016-02-22
