Design of Highly Enantioselective Organocatalysts Based on Molecular Recognition
收藏NIAID Data Ecosystem2026-03-06 收录
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Various organocatalysts have been designed based on molecular recognition to catalyze the asymmetric direct aldol reaction of ketones with aryl and alkyl α-keto acids, affording β-hydroxyl carboxylic acids with a tertiary stereogenic center with excellent enantioselectivities of up to 98% ee. A linear effect was observed for the reaction, demonstrating a single molecule of the catalyst involved in the catalysis.
创建时间：
2016-05-05
