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Domino Coupling Relay Approach to Polycyclic Pyrrole-2-carboxylates

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https://figshare.com/articles/dataset/Domino_Coupling_Relay_Approach_to_Polycyclic_Pyrrole_2_carboxylates/3273667
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资源简介:
CuBr2-catalyzed three-component coupling of N-benzylallylamine, ethyl glyoxalate, and terminal alkynes afforded glycine-tethered 1,6-enynes, which were further transformed into polycyclic pyrrole-2-carboxylates via novel cycloisomerization/Diels−Alder cycloaddition/dehydrogenation sequence under iridium-catalyzed conditions.
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2016-05-05
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