Single and Multiple Insertion of Carbon−Carbon Triple Bonds into the Palladium−Aryl Bond of Cationic and Neutral Arylpalladium Complexes with a 2,2‘-Bipyridine Ligand
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下载链接：
https://figshare.com/articles/dataset/Single_and_Multiple_Insertion_of_Carbon_Carbon_Triple_Bonds_into_the_Palladium_Aryl_Bond_of_Cationic_and_Neutral_Arylpalladium_Complexes_with_a_2_2_-Bipyridine_Ligand/3761937
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资源简介：
Dimethyl acetylenedicarboxylate reacts with PdI(C6H3Me2-3,5)(bpy) in the presence of
AgBF4, causing rapid insertion of three acetylene molecules into the Pd−C bond to afford
(Z = COOMe), whereas a
similar reaction without AgBF4 gives the product of a single insertion of the carbon−carbon
triple bond, Pd(I)(CZCZC6H3Me2-3,5)(bpy).
创建时间：
2016-08-26
