Locked Planarity: A Strategy for Tailoring Ladder-Type π‑Conjugated Anilido–Pyridine Boron Difluorides
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A novel series of syn- and anti-ladder-type anilido–pyridine boron difluorides (APBDs) were synthesized by stepwise incorporation of boron into laddered ligands. The boron coordination-locked strategy endows the ladder-type APBDs with a stiff conformation, which results in a substantial bathochromic shift of their absorption spectra and a narrowed HOMO–LUMO energy gap, reinforcing the compounds for potential applications in organic electronics.
创建时间：
2016-02-18
