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Source Data for Calculations, UV-vis-NIR, and NMR for A Tetrahedral Neptunium(V) Complex

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Source Data for Calculations, UV-vis-NIR, and NMR for A Tetrahedral Neptunium(V) Complex

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2024-04-20

锕系元素配合物化学

C-H键活化反应

Reduction of the tetravalent complex [{2,5-[(C4H3N)CPh2]2[C4H2N(Me)]}ThCl2 (THF)]·THF (2) of the tripyrrolide dianion 2,5-[(C4H3N)CPh2]2C4H2N(Me) afforded different products depending on the reaction

NIAID Data Ecosystem70

Synthesis, Characterization, and Reactivity of a Uranyl β-Diketiminate Complex

锕系元素配合物化学

铀酰配合物合成与表征

Addition of 1 equiv of Li(Ar2nacnac) (Ar2nacnac = (2,6-iPr2C6H3)NC(Me)CHC(Me)N(2,6-iPr2C6H3)) to an Et2O suspension of UO2Cl2(THF)3 generates the uranyl dimer [UO2(Ar2nacnac)Cl]2 (1) in good yield. A

NIAID Data Ecosystem60

Carbon Dioxide Activation with Sterically Pressured Mid- and High-Valent Uranium Complexes

锕系元素配合物化学

二氧化碳催化转化

Sterically pressured mid- to high-valent uranium complexes with an aryloxide substituted triazacyclononane ligand scaffold, [((RArO)3tacn)3–], were studied for carbon dioxide activation and transforma

NIAID Data Ecosystem40

In-Plane Thorium(IV), Uranium(IV), and Neptunium(IV) Expanded Porphyrin Complexes

锕系元素配合物化学

金属-配体共价性分析

Here we report the first series of in-plane thorium(IV), uranium(IV), and neptunium(IV) expanded porphyrin complexes. These actinide (An) complexes were synthesized using a hexa-aza porphyrin analo

NIAID Data Ecosystem70

Dithio- and Diselenophosphinate Thorium(IV) and Uranium(IV) Complexes: Molecular and Electronic Structures, Spectroscopy, and Transmetalation Reactivity

锕系元素配合物化学

金属转移反应

We report a comparison of the molecular and electronic structures of dithio- and diselenophosphinate, (E2PR2)1– (E = S, Se; R = iPr, tBu), with thorium(IV) and uranium(IV) complexes. For the thorium

NIAID Data Ecosystem40

Source Data for Calculations, UV-vis-NIR, and NMR for A Tetrahedral Neptunium(V) Complex

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