Chromium–Chromium Interaction in a Binuclear Mixed-Valent Cr<sup>I</sup>–Cr<sup>II</sup> Complex
收藏NIAID Data Ecosystem2026-03-09 收录
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A mixed-valent CrI–CrII binuclear complex, {κ1,κ2,κ3-N,P,P-cyclo[(Ph)PCH2N(CH2Ph)CH2]}2(CrCl2)[Cr(μ-Cl)(AlClMe2)]·4toluene (1), of a P2N2 cyclic ligand was obtained upon treatment of the chromium precursor with alkylaluminum. Complex 1 was accessible from either its trivalent or divalent precursors, and density functional theory calculations revealed the presence of only σ- and π-orbital interactions in the Cr–Cr bond.
创建时间：
2016-02-16
