An Orthogonal Dynamic Covalent Chemistry Tool for Ring-Opening Polymerization of Cyclic Oligochalcogenides on Detachable Helical Peptide Templates
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Dynamic Covalent Metathesis in the CC/CN Exchange between Knoevenagel Compounds and Imines
Fast and reversible dynamic covalent CC/CN exchange takes place without catalyst in nonpolar solvents between barbiturate-derived Knoevenagel (Kn) compounds and imines. A detailed study of the react
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Dynamic covalent chemistries of thermosetting polymer for recyclability and intelligent lubrication
Recently, the focus of materials research has shifted toward intelligent materials and structures with customizable properties and stimulus-responsive functions. Here, a recyclable thermosetting epoxy
中国科学院兰州化学物理研究所科学数据中心2025-12-12 更新100
Adaptive Encapsulation of ω‑Amino Acids and Their Guanidinium–Amide Congeners
The binding and the encapsulation of the 6-aminohexanoic acid (1) and 11-aminoundecanoic acid (2) are achieved in aqueous solution and in crystalline Pyrene-box cages. Unexpectedly, the amino-guanidin
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Regulation of Axial Chirality through Dynamic Covalent Bond Constrained Biaryls
A strategy of dynamic covalent chemistry within constrained biaryls was developed for the modulation of axial chirality. The ring fusion partners of amide and aldehyde allowed the manipulation of ring
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Rotaxane Formation under Thermodynamic Control
Thermodynamic control operates in the synthesis of a [2]rotaxane based upon the dibenzylammonium ion/crown ether recognition motif. When dibenzo[24]crown-8 is added to an acetonitrile solution contain
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