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An Unprecedented Oxidative Migration of a Methyl Group from 2-(2‘,6‘-Dimethylphenylazo)-4-methylphenol Mediated by Ruthenium and Osmium

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NIAID Data Ecosystem2026-03-06 收录
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An unprecedented chemical transformation of 2-(2‘,6‘-dimethylphenylazo)-4-methylphenol has been observed upon its reaction with [M(PPh3)3X2] (M = Ru, Os; X = Cl, Br) whereby one methyl group from the phenyl ring of the arylazo fragment migrates to the metal center via oxidation to CO.

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2003-11-17
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