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Dimeric Diorganotin Dications: Structure and Catalytic Activity in Alcohol Acetylation

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Figshare2007-07-30 更新2026-04-28 收录
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https://figshare.com/articles/dataset/Dimeric_Diorganotin_Dications_Structure_and_Catalytic_Activity_in_Alcohol_Acetylation/12065034
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We report the stabilization of the Sn2 diorganotin(IV) dication [Ph(L1)Sn(μ-OH)2Sn(L1)Ph]2+(1-CB11H12)-2 (2), where L1 is 1-{2,6-(MeOCH2)2C6H3}, which in contrast to the rare analogues prepared thus far does not contain a coordinated water molecule. Compound 2 exhibits high catalytic activity in the acetylation of alcohols.
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2007-07-30
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