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Radical Mechanism in the Elimination of 2-Arylsulfinyl Esters

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Figshare2016-02-20 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Radical_Mechanism_in_the_Elimination_of_2_Arylsulfinyl_Esters/2517787
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The mechanism of the dehydrosulfenylation of 2-arylsulfinyl esters was investigated. The reaction was found to follow a homolytic cleavage mechanism as verified by electrospray ionization tandem mass spectrometry and experimental work. Rearranged sulfoxides are obtained as byproduct during the elimination reaction.
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2016-02-20
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