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Designing Higher Surface Area Metal–Organic Frameworks: Are Triple Bonds Better Than Phenyls?

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Figshare2016-02-20 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Designing_Higher_Surface_Area_Metal_Organic_Frameworks_Are_Triple_Bonds_Better_Than_Phenyls_/2512117
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资源简介:
We have synthesized, characterized, and computationally validated the high Brunauer–Emmett–Teller surface area and hydrogen uptake of a new, noncatenating metal–organic framework (MOF) material, NU-111. Our results imply that replacing the phenyl spacers of organic linkers with triple-bond spacers is an effective strategy for boosting molecule-accessible gravimetric surface areas of MOFs and related high-porosity materials.
创建时间:
2016-02-20
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