Rhodium-Catalyzed Cycloisomerization of 2‑Silylethynyl Phenols and Anilines via 1,2-Silicon Migration
收藏Figshare2016-03-28 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Rhodium_Catalyzed_Cycloisomerization_of_2_Silylethynyl_Phenols_and_Anilines_via_1_2_Silicon_Migration/3121237
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It has been established that a cationic rhodium(I)/BINAP complex catalyzes the cycloisomerization of 2-silylethynylphenols, leading to 3-silylbenzofurans, via 1,2-silicon migration. Similarly, the cycloisomerization of 2-silylethynylanilines, leading to 3-silylindoles, via 1,2-silicon migration was catalyzed by a cationic rhodium(I)/H8–BINAP complex.
创建时间：
2016-03-28
