Novel Trialkanolamine Derivatives of Tin of the Type [N(CH2CMe2O)2(CH2)nOSnOR]m (m = 1, 2; n = 2, 3; R = t‑Bu, 2,6-Me2C6H3) and Related Tri- and Pentanuclear Tin(IV) Oxoclusters. Syntheses and Molecular Structures
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https://figshare.com/articles/dataset/Novel_Trialkanolamine_Derivatives_of_Tin_of_the_Type_N_CH_sub_2_sub_CMe_sub_2_sub_O_sub_2_sub_CH_sub_2_sub_sub_i_n_i_sub_OSnOR_sub_i_m_i_sub_i_m_i_1_2_i_n_i_2_3_R_i_t_i_Bu_2_6_Me_sub_2_sub_C_sub_6_sub_H_sub_3_sub_and_Related_Tri_and_Pentanuclear_Tin_IV_Ox/2442352
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The syntheses of the novel alkanolamine N(CH2CMe2OH)2(CH2CH2CH2OH) (2), the novel aminotrialkoxides of tin of the type [N(CH2CMe2O)2(CH2)nOSnOR]m (3: m = 1, n = 2, R = t-Bu; 4: m = 2, n = 3, R = t-Bu; 5: m = n = 2, R = 2,6-Me2C6H3; 6: m = 2, n = 3, R = 2,6-Me2C6H3) and the related trinuclear tin oxoclusters [(LSnOSnL)(LSnOR)] [L = N(CH2CMe2O)2(CH2CH2O), 7: R = t-Bu; 8: R = 2,6-Me2C6H3] and the pentanuclear tin oxocluster [LSnOSn(OH)2OSnL·2LSnOH], [9, L = N(CH2CMe2O)2(CH2CH2O)] are reported. The compounds are characterized by elemental analyses, multinuclear (1H, 13C, 119Sn, 1H-1H cosy, 1H-13C HSQC) NMR spectroscopy, electrospray ionization mass spectrometry, and single crystal X-ray diffraction analyses (3, 4·C7H8, 5, 7, 8·0.5C7H8, 9·6H2O).
创建时间：
2016-02-19
