Synthesis of Free-Base 10-Azacorroles
收藏NIAID Data Ecosystem2026-03-09 收录
下载链接：
https://figshare.com/articles/dataset/Synthesis_of_Free-Base_10-Azacorroles/3413077
下载链接
链接失效反馈官方服务：
资源简介：
A novel
synthetic protocol has been developed for free-base 10-azacorroles.
Ni(0)-mediated homocoupling of nitrogen-bridged bisdipyrrin Zn(II)
complexes afforded a series of free-base 5,15-diaryl-10-azacorroles
in good yields. Pd(II) and Cu(II) complexes have been prepared through
metalation of free-base 10-azacorroles. Optical and electrochemical
properties of 10-azacorrole metal complexes can be tuned by meso-aryl substituents and central metals. Cyclic voltammetry
and theoretical calculations elucidated that the central metals of
10-azacorroles significantly affected their electronic properties.
创建时间：
2016-06-13
