Iron-Catalyzed Borylation of Alkyl, Allyl, and Aryl Halides: Isolation of an Iron(I) Boryl Complex
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https://figshare.com/articles/dataset/Iron_Catalyzed_Borylation_of_Alkyl_Allyl_and_Aryl_Halides_Isolation_of_an_Iron_I_Boryl_Complex/2237239
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Activation of B2pin2 with tBuLi facilitates the Fe-catalyzed borylation of alkyl, allyl, benzyl, and aryl halides via the formation of Li[B2pin2(tBu)] (1). The reaction of 1 with a representative iron phosphine precatalyst generates the unique iron(I) boryl complex [Fe(Bpin)(dpbz)2] (2).
创建时间：
2016-02-16
