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Crystal Growth of Novel Osmium-Containing Triple Perovskites

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https://figshare.com/articles/dataset/Crystal_Growth_of_Novel_Osmium-Containing_Triple_Perovskites/3610731
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Single crystals of two new osmium-containing triple perovskites, Ba3LiOs2O9 and Ba3NaOs2O9, were grown from reactive molten hydroxide fluxes in sealed silver tubes. They crystallize in the space group P63/mmc with lattice parameters of a = 5.8025(1) Å, c = 14.1468(4) Å for Ba3LiOs2O9 and a = 5.8858(1) Å, c = 14.3451(5) Å for Ba3NaOs2O9. The magnetic susceptibility of these osmates indicates significant Os−Os coupling within the octahedra pair.
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2016-08-17
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