Capture–Collapse Heterocyclization: 1,3-Diazepanes by C–N Reductive Elimination from Rhodacyclopentanones
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https://figshare.com/articles/dataset/Capture_Collapse_Heterocyclization_1_3-Diazepanes_by_C_N_Reductive_Elimination_from_Rhodacyclo_pentanones/3803718
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资源简介：
Rhodacyclopentanones derived from
carbonylative C–C activation
of cyclopropyl ureas can be “captured” by pendant nucleophiles
prior to “collapse” to 1,3-diazepanes. The choice of
N-substituent on the cyclopropane unit controls the oxidation level
of the product, such that C4–C5 unsaturated or saturated systems
can be accessed selectively.
创建时间：
2016-09-09
