A Novel Ditopic Receptor and Reversal of Anion Binding Selectivity in the Presence and Absence of Bound Cation
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https://figshare.com/articles/dataset/A_Novel_Ditopic_Receptor_and_Reversal_of_Anion_Binding_Selectivity_in_the_Presence_and_Absence_of_Bound_Cation/3355222
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资源简介:
A calix[4]arene-derived ditopic receptor 1 has been synthesized. In the absence of Na+, the receptor binds acetate in preference to diphenyl
phosphate (as the tetrabutylammonium salts), but in the presence of Na+, the selectivity is reversed and the receptor, instead, binds diphenyl
phosphate, and not acetate, which preferentially forms a salt ion-pair in free solution.
创建时间:
2016-05-07



