Branch-Selective Allylic C–H Carboxylation of Terminal Alkenes by Pd/sox Catalyst
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A ligand-controlled branch-selective allylic C–H carboxylation through Pd catalysis is described. The developed catalytic system, which consists of Pd(OAc)2, sulfoxide–oxazoline (sox) as a ligand and benzoquinone as an oxidant, couples terminal alkenes and carboxylic acids to furnish the corresponding branched allylic esters with high regioselectivity.
创建时间：
2016-02-17
