Anionic Iron Complexes with a Bond between an Ate-Type Pentacoordinated Germanium and an Iron Atom
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https://figshare.com/articles/dataset/Anionic_Iron_Complexes_with_a_Bond_between_an_Ate_Type_Pentacoordinated_Germanium_and_an_Iron_Atom/2461837
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资源简介：
The first stable anionic iron(0) complexes bearing an
ate-type
pentacoordinated germanium(IV) ligand were synthesized. The X-ray
crystallographic analysis shows trigonal-bipyramidal and piano-stool
geometries of germanium and iron, respectively. The complexes have
moderately electron-rich iron centers and polar Ge–Fe bonds
which can be cleaved by oxidation.
创建时间：
2012-12-10
