[B(O2C2(CF3)4)2]− ([FPB]−): Repurposing This Weakly Coordinating Anion for Solid-State Molecular Organometallic (SMOM) Chemistry
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https://figshare.com/articles/dataset/_B_O_sub_2_sub_C_sub_2_sub_CF_sub_3_sub_sub_4_sub_sub_2_sub_sup_sup_FPB_sup_sup_Repurposing_This_Weakly_Coordinating_Anion_for_Solid-State_Molecular_Organometallic_SMOM_Chemistry/28927924
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The perfluoropinacol borate-based anion [B(O2C2(CF3)4)2]−, [FPB]–, is developed as a weakly coordinating anion for single-crystal to single-crystal organometallic solid/gas reactivity, resulting in the isolation and characterization (including periodic DFT and IGMH analysis) of the σ-alkane complex [Rh(Cy2PCH2CH2PCy2)(exo-η2η2-norbornane)][FPB]. The synthetically useful solvent-free Na+ salt, Na[FPB], and oxonium acid [H(OEt2)2][FPB] are also reported.
创建时间：
2025-05-04
