Oligometallic Template Strategy for Ring-Closing Olefin Metathesis: Highly Cis- and Trans-Selective Synthesis of a 32-Membered Macrocyclic Tetraoxime
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https://figshare.com/articles/dataset/Oligometallic_Template_Strategy_for_Ring_Closing_Olefin_Metathesis_Highly_Cis_and_Trans_Selective_Synthesis_of_a_32_Membered_Macrocyclic_Tetraoxime/2975650
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资源简介:
An oligometallic template effect was observed on the cis/trans
selectivity of a 32-membered macrocyclic tetraoxime in ring-closing
olefin metathesis of an acyclic diallyl derivative H4L; the metathesis
of heterotrinuclear complex LZn2M (M = Ca2+, La3+) afforded the
cis isomer, whereas uncomplexed H4L gave the trans isomer.
创建时间:
2016-06-03



