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Oligometallic Template Strategy for Ring-Closing Olefin Metathesis: Highly Cis- and Trans-Selective Synthesis of a 32-Membered Macrocyclic Tetraoxime

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Oligometallic_Template_Strategy_for_Ring_Closing_Olefin_Metathesis_Highly_Cis_and_Trans_Selective_Synthesis_of_a_32_Membered_Macrocyclic_Tetraoxime/2975650
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An oligometallic template effect was observed on the cis/trans selectivity of a 32-membered macrocyclic tetraoxime in ring-closing olefin metathesis of an acyclic diallyl derivative H4L; the metathesis of heterotrinuclear complex LZn2M (M = Ca2+, La3+) afforded the cis isomer, whereas uncomplexed H4L gave the trans isomer.
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2016-06-03
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