An Unexpected Two-Group Migration Involving a Sulfonynamide to Nitrile Rearrangement. Mechanistic Studies of a <i>Thermal</i> N → C Tosyl Rearrangement
收藏NIAID Data Ecosystem2026-03-06 收录
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We report the discovery of the first double-barreled thermal rearrangement of a sulfonynamide and a methoxybenzyl to a nitrile and the first rearrangement of an SO2 group from sulfonamide to ketoimine. The rearrangement occurs under surprisingly mild conditions (onset at 100 °C in the melt).
创建时间：
2016-05-06
