A Neutral, Carbene-Stabilized Gold(III) Triazide
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https://figshare.com/articles/dataset/A_Neutral_Carbene-Stabilized_Gold_III_Triazide/4029147
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资源简介：
The
first neutral gold(III) triazido compounds stabilized by N-heterocyclic
carbenes were prepared and structurally characterized. Various 1,3-dipolar
cycloaddition reactions were examined with these compounds. Isothiocyanates
and tBuNC gave the expected cycloaddition
products; however, these were accompanied by reduction to gold(I).
Examination of the photophysical properties of the triazido compounds
in solution revealed that photoreduction to gold(I) species occurs
readily.
创建时间：
2016-10-18
