Mn8@Na8 Cube-in-Cube SBBs-Based Heterometallic Coordination Network with Unprecedented (39.46)8 Topological Mn8(μ4‑OMe)6 Cubes
收藏Figshare2016-02-19 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Mn_sub_8_sub_Na_sub_8_sub_Cube_in_Cube_SBBs_Based_Heterometallic_Coordination_Network_with_Unprecedented_3_sup_9_sup_4_sup_6_sup_sub_8_sub_Topological_Mn_sub_8_sub_sub_4_sub_OMe_sub_6_sub_Cubes/2428702
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资源简介：
A novel body-centered cubic antiferromagnetic heterometal-coordination network Na4Mn8(μ4-OMe)6(μ4-MeCO2)12 ·2MeCO2 based on Mn8@Na8 cube-in-cube supramolecular building blocks has been synthesized, in which the unprecedented cubic (39.46)8 topological Mn8(μ4-OMe)6 cube with capped oxygen of five coordination is first revealed. Interestingly, the cube-in-cube Mn8@Na8 in combination with coordinated oxygen atoms makes up the unique nested Mn8O6@O24@Na8 triple-shell structure, in which the inner Mn8 cube is penetrated by the O6 octahedron but is enclosed by a larger O24 truncated cube that is further surrounded by a still larger Na8 cube.
创建时间：
2016-02-19
