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Metal Nitrite: A Powerful Oxidizing Reagent

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Figshare2016-02-23 更新2026-04-29 收录
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An efficient and simple source of nitroso reagents and their oxidation reactions are described. The combination of a Lewis acid and a metal nitrite was applied to the oxidation of silyl enol ethers. Amino acid and peptide derivatives were easily accessed through in situ C–C bond cleavage of fully substituted silyl enol ethers upon oxidation.

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2016-02-23
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