Synthesis of Adipic Aldehyde by <i>n</i>‑Selective Hydroformylation of 4‑Pentenal
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资源简介：
Several phosphine and phosphite ligands were tested in the hydroformylation of 4-pentenal to adipic aldehyde, a versatile starting material for industrially very relevant compounds. By varying the ligand structure we were able to increase the selectivity toward adipic aldehyde to >95%. Additionally, two molecular structures of important catalytic intermediates [(bisphosphite)RhH(CO)2] and one structure of a previously unknown catalyst decomposition product were obtained.
创建时间：
2016-02-15
