Reactivity Study of a Pyridyl-1-azaallylgermanium(I) Dimer: Synthesis of Heavier Ether and Ester Analogues of Germanium
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https://figshare.com/articles/dataset/Reactivity_Study_of_a_Pyridyl_1_azaallylgermanium_I_Dimer_Synthesis_of_Heavier_Ether_and_Ester_Analogues_of_Germanium/3119059
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资源简介：
The reactivity study of a pyridyl-1-azaallylgermanium(I)
dimer LGe–GeL [1; L = N(SiMe3)C(Ph)C(SiMe3)(C5H4N-2)] with different stoichiometric
ratios of elemental selenium and tellurium is described. The reactions
of 1 with 1 equiv of selenium and tellurium afforded
the first examples of heavier ether analogues of germanium, bis(germylene)
selenide and telluride LGe(μ-E)GeL [E = Se (2)
and Te (3)], respectively. Meanwhile, the reactions of 1 with 2 equiv of selenium and tellurium gave the heavier
ester analogues LGeE(μ-E)GeL [E = Se (4) and (5)]. All compounds have been characterized by
X-ray crystallography and multinuclear NMR spectroscopy.
创建时间：
2016-03-29
