Rhodium(I)-Catalyzed Pauson–Khand-type [3 + 2 + 1] Cycloaddition Reaction of Ene-Vinylidenecyclopropanes and CO: A Highly Regio- and Stereoselective Synthetic Approach for the Preparation of Aza- and Oxa-Bicyclic Compounds
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https://figshare.com/articles/dataset/Rhodium_I_Catalyzed_Pauson_Khand_type_3_2_1_Cycloaddition_Reaction_of_Ene_Vinylidenecyclopropanes_and_CO_A_Highly_Regio_and_Stereoselective_Synthetic_Approach_for_the_Preparation_of_Aza_and_Oxa_Bicyclic_Compounds/2511388
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资源简介：
In this paper, a novel Rh(I)-catalyzed Pauson–Khand-type
[3 + 2 + 1] cycloaddition reaction of ene-vinylidenecyclopropanes
(Ene-VDCPs) and carbon monoxide (CO) has been developed to furnish
a series of aza- and oxa-bicyclic compounds in moderate to good yields
in a highly regio- and diastereoselective manner, which provides an
alternative and efficient synthetic approach for the access of bicyclic
cyclohexanone frameworks. The substrate scope and limitations and
a plausible mechanism are discussed.
创建时间：
2012-06-25
