Dataset for <b>Global distribution and drivers of </b><b>leaf maximum carboxylation rate</b>
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The maximum carboxylation rate of Rubisco (V<sub>cmax</sub>) is a crucial parameter in terrestrial biosphere models (TBMs) for simulating photosynthetic carbon assimilation. Most TBMs, however, prescribe V<sub>cmax </sub>as a constant within each plant functional type, neglecting spatial variability and limiting the accuracy of terrestrial carbon cycle estimates. Although several attempts have been made to map V<sub>cmax</sub> globally, its large-scale patterns and controlling factors remain poorly understood. Here, we compiled 6386 in situ measurements of V<sub>cmax</sub> together with leaf nitrogen (LNC), phosphorus (LPC), and mass per area (LMA), and used machine learning to generate a global V<sub>cmax</sub> map and identify its drivers. The predicted V<sub>cmax</sub> shows strong agreement with three existing products (R<sup>2</sup> ≥ 0.74) and have the best performance when validated against independent field data. We further find that leaf nutrients, climate, and soil jointly regulate global V<sub>cmax</sub> variation, with LNC, LPC, and soil pH emerging as primary predictors. These results advance understanding of the factors controlling V<sub>cmax</sub>, and suggest that projections of photosynthetic capacity and terrestrial carbon fluxes could be markedly improved by incorporating the interactive effects of leaf nutrient traits, climate, and soil properties into V<sub>cmax</sub> parameterization in TBMs.



