Recognition of Water−Acetonitrile−Water Cluster in a Tetraprotonated Picrate Salt of Octaaminocryptand
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https://figshare.com/articles/dataset/Recognition_of_Water_Acetonitrile_Water_Cluster_in_a_Tetraprotonated_Picrate_Salt_of_Octaaminocryptand/3043312
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资源简介:
Octaamino cryptand L (1,4,11,14,17,24,29,36-octaazapentacyclo[12.12.12.2.6,92.19,22231,34]tetratetraconta-(43),7,9(44),
19(41),20,22(42),31(39),32,34(40)-nonaene, N(CH2CH2NHCH2-p-xylyl-H2NHCH2CH2)3N), in tetraprotonated form shows encapsulation
of a water−acetonitrile−water cluster (1), whereas a molecule of water encapsulation inside the cryptand cavity is observed in the triprotonated
state (2), with picrate as counteranions. These two compounds were examined crystallographically. Thermal analysis supports the
crystallographic findings.
创建时间:
2016-02-29



