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Zwitterionic 1,2,3-Triazolium Amidate as a Catalyst for Photoinduced Hydrogen-Atom Transfer Radical Alkylation

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https://figshare.com/articles/dataset/Zwitterionic_1_2_3-Triazolium_Amidate_as_a_Catalyst_for_Photoinduced_Hydrogen-Atom_Transfer_Radical_Alkylation/11823339
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资源简介:
A zwitterionic 1,2,3-triazolium amidate was designed for use as an effective modular hydrogen-atom transfer catalyst for photoredox C–H functionalization. This zwitterionic amidate is stable yet amenable to single-electron oxidation for generating a highly reactive amidyl radical. In cooperation with an Ir-based visible-light photoredox catalyst, the optimal catalyst enables the efficient direct alkylation of the C–H bonds of various nitrogen- or oxygen-containing organic compounds.
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2019-12-02
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