Highly Productive α‑Alkylation of Ketones with Alcohols Mediated by an Ir–Oxalamidato/Solid Base Catalyst System
收藏Figshare2020-09-08 更新2026-04-28 收录
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https://figshare.com/articles/dataset/Highly_Productive_Alkylation_of_Ketones_with_Alcohols_Mediated_by_an_Ir_Oxalamidato_Solid_Base_Catalyst_System/12954968
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An Ir–oxalamidato complex in combination with a solid base (e.g., magnesium aluminometasilicate/Ca(OH)2) significantly improved the catalyst productivity in α-alkylation of methyl ketones with primary alcohols. Optimization through systematic variation of the oxalamidato ligand led to a practical turnover number (TON) of 10 000–40 000.
创建时间：
2020-09-08
