Oppolzer-Type Intramolecular Diels–Alder Cycloadditions via Isomerizations of Allenamides
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https://figshare.com/articles/dataset/Oppolzer_Type_Intramolecular_Diels_Alder_Cycloadditions_via_Isomerizations_of_Allenamides/2641171
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资源简介:
A new approach to Oppolzer’s intramolecular Diels–Alder cycloaddition (IMDA) through γ-isomerization of readily available N-tethered allenamides is described. These IMDA reactions are carried out in tandem with the allenamide isomerization or 1,3-H shift, leading to complex nitrogen heterocycles in a highly stereoselective manner.
创建时间:
2016-02-23



