Electrochemical Difluoromethylarylation of Alkynes
收藏Figshare2018-02-09 更新2026-04-29 收录
下载链接：
https://figshare.com/articles/dataset/Electrochemical_Difluoromethylarylation_of_Alkynes/5874099
下载链接
链接失效反馈官方服务：
资源简介：
An unprecedented radical difluoromethylarylation reaction of alkynes has been developed by discovering a new difluoromethylation reagent, CF2HSO2NHNHBoc. This air-stable and solid reagent can be prepared in one step from commercially available reagents CF2HSO2Cl and NH2NHBoc. The CF2H radical, generated through ferrocene-mediated electrochemical oxidation, participates in an unexplored alkyne addition reaction followed by a challenging 7-membered ring-forming homolytic aromatic substitution step to afford fluorinated dibenzazepines.
创建时间：
2018-02-09
